Enantioselective 1,1-arylborylation of alkenes: merging chiral anion phase transfer with Pd catalysis.
نویسندگان
چکیده
A palladium-catalyzed three-component coupling of α-olefins, aryldiazonium salts, and bis(pinacolato)diboron affords direct access to chiral benzylic boronic esters. This process is rendered highly enantioselective using an unprecedented example of cooperative chiral anion phase transfer and transition-metal catalysis.
منابع مشابه
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 137 9 شماره
صفحات -
تاریخ انتشار 2015